FORMATION OF WEAR RESISTANT COATINGS ON ALUMINUM ALLOYS BY CHROMIUM DEPOSITION FROM GAS-PHASE ORGANOMETALLIC COMPOUNDS
Abstract and keywords
Abstract (English):
The method of coatings producing by chemical vapor deposition from gas phase by pyrolysis of organometallic com-pounds of chromium on the aluminum alloy AL9 is described. For the research the “Barhos” liquid with bis-arene chromium organic compounds, containing bis-ethylbenzene chromium (322 ºC boiling point, decomposition temperature of the metal is 330 ºC), was selected. The chromium content in the liquid is not less than 16%.The deposition process depends on the gas-phase chromium: substrate temperature, reactor pressure, evaporator temperature, process duration. The deposition temperature (substrate temperature) is one of the major factors in the formation of coatings. It is determined, that the pyrolytic chromium coatings are characterized by high hardness (up to 16000 MPa) and wear resistance due to the amorphous structure, which allows them to improve the wear resistance of rubbing parts.

Keywords:
pyrolytic chromium coating, vapor deposition bis-arene chromium compounds, hardness, wear resistance.
Text
Text (PDF): Read Download
References

1. Solodkova L.N., Kudryavtsev V.N. Electrolyticchromeplating. Moscow: Globus, 2007. 191 p.

2. Lai’ner V.I. Protective coatings of metals. Moscow: Metallurgy, 1974. 559 p.

3. SyrkinV.G. CVD - method. Chemical vapor deposition. Moscow: Nauka, 2000. 496 p.

4. Powell K., Oxley J., Blocher J. Vapour Deposition. Under the editorship of C. Powell. Moscow: Atomizdat, 1970. 472 p.

5. Samsonov G.V., Epik A.P. Refractory coating. Moscow: Metallurgy, 1973. 400 p.

6. Razuvaev G.A., Gribov B.G. et. al. Organometallic compounds in electronics. Moscow: Nauka, 1972. 479 p.

7. Syrkin V.G. Carbonyl metals. Moscow: Metallurgy, 1978. 256 p.

8. Zorin A.D., Vanchagova V.K., Umilin V.A. et. al. Composition and nature of the impurities in pyrolytic chromium films. In the book: All-Union conference on the use of organometallic compounds for metal and oxide coatings, 3rd: Abstracts. Gor’kiy, 1980. Pp. 75-76.

9. Author certificate no. 1246636 USSR. ICI S23S 11/02. Coaster vapor (gas) phase. Yu.M. Lakhtin, Ya.D. Kogan, A.P. Gorovoy, V.M. Strulev. 1984.

Login or Create
* Forgot password?